Los científicos Jacques Charles y Joseph Gay-Lussac estudiaron como se comportaba la presión y el volumen de un gas cuando variaba la temperatura. Descubrieron que al calentar un gas el volumen de este se expandía, y al enfriarlo se contraía. La Ley de Gay-Lussac, formulada por Joseph Louis Gay-Lussac enestablece que la presión de un gas es directamente proporcional a su temperatura, siempre que el volumen y la cantidad de gas se mantengan constantes.
La ley de Charles y Gay-Lussac, frecuentemente llamada ley de Charles o ley de Gay-Lussac, es una de las leyes de los gases ideales. Relaciona el volumen y la temperatura de una cierta cantidad de gas ideal, mantenido a una presión constante, mediante una constante de proporcionalidad directa.
La ley de Charles (también conocida como la ley de los volúmenes) es una ley experimental de los gases que describe cómo los gases tienden a expandirse cuando se calientan. Las leyes básicas que explican el comportamiento del estado gaseoso, son la de Boyle, Charles, Gay-Lussac y ley combinada. Todas ellas requieren que la cantidad de gas, en el sistema estudiado, sea constante.
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